Using a novel polymerization process, MIT chemical engineers have created a new material that is stronger than steel and as light as plastic, and can be easily manufactured in large quantities. The new material is a two-dimensional polymer that self-assembles into sheets, unlike all other polymers, which form one-dimensional, spaghetti-like chains. Until now, scientists had believed it was impossible to induce polymers to form 2D sheets. Such a material could be used as a lightweight, durable coating for car parts or cell phones, or as a building material for bridges or other structures. MIT’s Carbon P Dubbs Professor of Chemical Engineering Mr Michael Strano said “We don’t usually think of plastics as being something that you could use to support a building, but with this material, you can enable new things. It has very unusual properties and we’re very excited about that.”Polymers, which include all plastics, consist of chains of building blocks called monomers. These chains grow by adding new molecules onto their ends. Once formed, polymers can be shaped into three-dimensional objects, such as water bottles, using injection molding. Polymer scientists have long hypothesized that if polymers could be induced to grow into a two-dimensional sheet, they should form extremely strong, lightweight materials. However, many decades of work in this field led to the conclusion that it was impossible to create such sheets. One reason for this was that if just one monomer rotates up or down, out of the plane of the growing sheet, the material will begin expanding in three dimensions and the sheet-like structure will be lost.However, in the new study, MIT researchers came up with a new polymerization process that allows them to generate a two-dimensional sheet called a polyaramide. For the monomer building blocks, they use a compound called melamine, which contains a ring of carbon and nitrogen atoms. Under the right conditions, these monomers can grow in two dimensions, forming disks. These disks stack on top of each other, held together by hydrogen bonds between the layers, which make the structure very stable and strong. The researchers found that the new material’s elastic modulus, a measure of how much force it takes to deform a material, is between four and six times greater than that of bulletproof glass. They also found that its yield strength, or how much force it takes to break the material, is twice that of steel, even though the material has only about one-sixth the density of steel.MIT researchers are now studying in more details how this particular polymer is able to form 2D sheets, and they are experimenting with changing its molecular makeup to create other types of novel materials.The researchers have filed for two patents on the process they used to generate the material, which they describe in a paper appearing in Nature. MIT postdoc Yuwen Zeng is the lead author of the study.The research was funded by the Center for Enhanced Nanofluidic Transport an Energy Frontier Research Center sponsored by the US Department of Energy Office of Science and the Army Research Laboratory.